What innovations for affordable biodegradable materials?

The packaging industry is gradually turning towards more sustainable packaging solutions, composed mainly of bio-based and/or biodegradable materials. Although this transition is necessary, finding a balance between environmental and economic aspects is crucial.

In this article, we will address the financial issues that condition the widespread adoption of biodegradable materials.

What are the main biodegradable plastic materials?

 

PLA

This aliphatic polyester is obtained from sugars such as corn starch, beet, or sugarcane.

It is the oldest and best-known biodegradable plastic, compostable in an industrial environment.

PHA

This polymer is naturally produced by microorganisms, 100% biodegradable and compostable both domestically and industrially.

PHA is mainly formed by injection molding.

PBS/PBSA

Poly(butylene succinate), or PBS, is also a polyester. While it was long produced from petro-sourced materials, current PBS is generally 50% bio-based and mostly compostable.

PBSA, or polybutylene succinate adipate, is 35% bio-based, very flexible, and biodegradable.

Le PBAT

Poly(butylene adipate terephthalate) is a biodegradable polyester copolymer. Highly flexible, it is a very good candidate for replacing PE film packaging.

Other materials and innovations

Other materials exist, including starch-based compounds, cellulose, and BioTPE. Among these partially bio-based materials, some references are also biodegradable.

 

Biodegradable under what conditions? Industrial compost Home compost Soil Water
BioTPE (TPU, SEBS, etc.) Some references No No No
PLA Yes No No No
PHA Yes Yes Yes Yes
PBS/PBSA Yes Yes Yes No
PBAT/PCL Yes Yes Yes No
Cellulosic Some references Some references Some references Some references
Starch based Yes Yes Yes Some references

Source: Presentation of NaturePlast during the Polyvia Materials Purchasing Day, organized in October 2021.

 

 

    The importance of accelerated biodegradation 

Most biodegradable polymers on the market are certified as biodegradable for thin products, around a hundred micrometers thick, and some manufacturers achieve up to a millimeter in standardized tests for home composting, but without certification.

Fortunately, it is possible to accelerate this biodegradation by adding additives (including enzymes and bacteria) or by mixing the material with a biodegradable polymer such as CareTips® resin.

 

Biodegradable polymers: more expensive than traditional plastics

According to Polyvia, in October 2023, the prices of polyethylene were as follows:

  • LDPE : between 1,55 and 1,65 €/kg 
  • HDPE : between 1,60 and 1,70 €/kg 
  • LLDPE : between 1,75 and 1,90 €/kg 

Comparing these figures with the prices of bioplastics, we can see that:

  • BioPE is at least twice as expensive as HDPE or LDPE
  • The price gap reaches a factor of 5 for biodegradable polymers such as PHA and PBS

 

Polymer Availability Price range (€/kg) Biodegradable
BioPET Limited offers 2 to 2,5 No
BioPE High demand, tight market 3 to 3,5 No
BioPP Limited capacities 3,5 No
BioPA  Often made to order or high demand 6 to 18 No
BioTPE (TPU, SEBS, etc.) Often made to order 5 to 8 In some cases
PLA High demand, new players entering 3 to 3,5 Yes
PHA Limited capacities 6 to 8 Yes
PBS High demand, tight market 4 to 8 Yes
Cellulosic Good 4 to 6 In some cases
Starch based Good 4 to 5 Yes

Source: Presentation of NaturePlast during the Polyvia Materials Purchasing Day, organized in October 2021.

 

What are the financial constraints for manufacturers of biodegradable polymers?

 

  • Cost of raw materials

As mentioned earlier, the high costs of bioplastics do not encourage industrialists to use these materials.

These costs are partly due to the use of more expensive raw materials such as starch, vegetable oils, and cane sugar. However, this situation is expected to evolve thanks to innovation.

 

  • Cost of adapting production equipment

The production of bioplastics requires different manufacturing processes from those used for traditional plastics, notably involving processes from the biotechnology sector.

Adapting current processes requires investments and thus entails additional costs for industrialists.

 

How to generalize biodegradable alternatives and increase their profitability?

 

Economies of scales

This is one of the main levers to reduce the cost of biodegradable materials: accelerating production to achieve economies of scale and increase the availability of these new materials.

The situation is expected to evolve in the right direction: according to European Bioplastics, the annual production capacity of bioplastics, whether bio-based or biodegradable, will be multiplied by 3 by 2027.

 

 

Innovation in production

Innovation also plays a significant role in reducing production costs. The emergence of new, simpler, and more environmentally friendly production processes will thus lead to obtaining less expensive materials.

Example: In the “classic” PLA manufacturing process, the lactide used is synthesized via a two-step process that is very expensive and generates a significant amount of waste.

Two Belgians, Michiel Dusselier and Bert Sels, have developed a PLA manufacturing method with a single step, using a catalyst based on synthetic zeolite. This innovative process, which is less energy-intensive and economical in raw materials, could reduce the total production cost of PLA by 30%.

 

Regulatory developments

The current European regulations tend to favor recycling, which slows down the emergence of biodegradable solutions.

However, the growth of biodegradable polymers seems inevitable, given the projected explosion in global plastic consumption.

 

Collection bags for biodegradable polymer piowaste: an ADEME approved application

Several European countries have already implemented the collection of biowaste, and France has been part of it since January 1, 2024.

For collection, Italy, which is a leader in this field, has opted for the use of biodegradable plastic bags. In France, ADEME also considers this solution relevant if it “contributes to increasing the quantities of valorized biowaste and does not disrupt waste treatment channels”.

 

Conclusion

Available biodegradable materials are increasing, and new innovations will continue to emerge in the coming years. However, their adoption by industrialists will depend on their accessibility in terms of both economics and production capacity.

Facing with the risks of scarcity or rising costs, packaging industry professionals will also need to demonstrate resilience, notably by integrating the use of multiple materials into their processes.

 

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